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Lithium T-Butoxide

Supplier From China
Dec-17-24

A lithium methanol solution typically refers to a solution where lithium salts (such as lithium chloride or lithium perchlorate) are dissolved in methanol, a type of alcohol. This kind of solution is often used in chemical and electrochemical applications, including battery technology, organic synthesis, and as a reagent in various laboratory processes.


Other Name Lithium Methoxide
English Name Lithium Methoxide Lithium methanolate Lithium methylate; methoxylithium Methanol, lithium salt
Molecular Formula CH3OLi Molecular weight 37.97
CAS No.: 865-34-9

1. Performance and use
This product is a methanol solution of lithium methoxide. It is mainly used as A shrinkage agent and strong base catalyst for organic synthesis transesterification reaction, and methoxylation agent for the preparation of vitamin A, vitamin B, sulfadiazine drugs. A small amount is used in pesticide production. It can also be used as a catalyst for edible fatty oils.


Battery Electrolytes: In some lithium battery chemistries, lithium methanol solutions can be used as electrolytes, though more commonly, solutions with organic carbonates are used.
Organic Synthesis: Lithium methanol solutions can act as a reagent or catalyst in organic reactions, particularly where a polar aprotic solvent is needed.
Chemical Analysis: In analytical chemistry, such solutions might be used in titrations or other procedures where lithium ions need to be present in a methanol medium.
Electrochemical Studies: Lithium methanol solutions are also used in electrochemical experiments to study the behavior of lithium ions in various solvents.

Price and Minimum Quantity

Price: $1
MOQ: Not Specified

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More Items Similiar to: Lithium T-Butoxide

GOLD Member
Oct-09-24

Lithium Tert-Butoxide

$1.20K
MOQ: 27  Metric Tonnes
Sample Available
Supplier From North York, Ontario, Canada
 
CAS 1907331
HS 2905199090

20LDrum


Product Name
Lithium tertbutoxide

CAS NO 1907331

Appearance


White Powder

Purity


99

Boiling Point


6870 C

Density


089 gmL at 20 C

Storage


28C

Application


Organotin Organometallic

Usage


Lithium tertbutoxide often be used in organic synthesis


Application
This product is one of the organometallic compound
Dec-17-24
 
Key Features of Lithium T-Butoxide:
Chemical Structure:

Formula: LiOC(CH3)3
Molecular Weight: 80.06 g/mol
Appearance: Typically, lithium t-butoxide is found as a white to off-white crystalline solid or powder.
Properties:

Strong Base: Lithium t-butoxide is a very strong base, much stronger than alcohols and water. It is commonly used in deprotonation reactions and to generate enolates from carbonyl compounds.
Non-Nucleophilic: Unlike some bases, lithium t-butoxide is relatively bulky, which reduces its nucleophilicity. This makes it particularly useful in reactions where a strong base is needed, but nucleophilic attack needs to be minimized.
Solubility: It is soluble in organic solvents such as tetrahydrofuran (THF), ether, and hexane but less soluble in alcohols and water. In solution, it can react with moisture and COâ??, so it is typically handled under inert gas like nitrogen or argon.
Applications:

Organic Synthesis: Lithium t-butoxide is widely used in organic chemistry for base-catalyzed reactions, such as:
Deprotonation: Used to deprotonate weak acids, particularly when generating enolates from carbonyl compounds.
Elimination Reactions: Often employed in E2 elimination reactions to generate alkenes.
Cross-Coupling Reactions: It can be used in various coupling reactions, such as Suzuki or Heck reactions, as a base to help facilitate the reaction.
Polymerization: It may be used in the polymerization of certain monomers, taking advantage of its strong basicity.
Preparation of Other Organolithium Compounds: Lithium t-butoxide is sometimes used in the synthesis of other organolithium reagents.
Handling and Safety:

Reactivity: Lithium t-butoxide is highly reactive and sensitive to moisture and air, so it should be stored in a dry, inert atmosphere (e.g., under nitrogen or argon).
Safety Precautions: As with many strong bases, it can cause severe burns if it comes into contact with skin or eyes. Proper protective equipment, such as gloves and goggles, should be worn when handling it.
Flammability: It should be kept away from open flames and sources of ignition, as it can be flammable when in powder form.

Lithium t-butoxide is a strong, non-nucleophilic base widely used in organic synthesis for deprotonation, elimination reactions, and in the preparation of other organolithium reagents. Its reactivity and strength make it a valuable tool in various chemical reactions, though care must be taken in its handling due to its sensitivity to moisture and its corrosive nature.
Sep-19-14

Lithium Ter-Butoxide

$1
MOQ: Not Specified
 
Appearance white or off-white solid pass
Assay y99%
Free ethanol 0.05%
Fe 0.005%
Ca 0.005%
Pb 0.002%
Na 0.005%
Cl 0.007%
N 0.005%

25kgs/drum
May-22-18

Lithium Tert-Butoxide

$10
MOQ: Not Specified
 
Appearance & Physical State:
clear yellow to brown solution
Density:
0.89
Melting Point:
ºC
Boiling Point:
67ºC
Flash Point:
-19ºC
Refractive Index:
1.52299 (124ºC)
Water Solubility:
vigorous reaction
Stability:
Stable to light, heat, air, carbon dioxide and strong acids.
Storage Condition:
Flammables area
Symbol:

GHS02
GHS05
GHS07
GHS08
GHS09
Sign:
Danger
hazard declaration:
H225; H251; H304; H314; H336; H361f; H373; H411
hazard declaration add:
Reacts violently with water.
waring notice:
P210; P235 + P410; P261; P273; P280; P301 + P310
RTECS:
UB8520000
Hazard Class:
4.2
Safety Statements:
S16-S26-S36/37/39-S43-S45-S6
HS Code:
2905143000
Packing Group:
III
WGK Germany:
3
RIDADR:
UN 2924
Risk Statements:
R11; R14; R35
Hazard Codes:
F; C
Aug-09-21
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CAS Number : 1310-65-2
Purity: 56.5%~99%
Origin: China
Payment term: T/T
Shipment term: CIF
MQO: 5MT
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.
Applications
1. Lithium ion batteries
2. Grease
3. Carbon dioxide scrubbing
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